运行时设置窗体最大化

  this.WindowState = FormWindowState.Maximized; 

public partial class MainForm : Form
{
    public MainForm()
    {
        InitializeComponent();

        // this is the default
        this.WindowState = FormWindowState.Normal;
        this.StartPosition = FormStartPosition.WindowsDefaultBounds;

        // check if the saved bounds are nonzero and visible on any screen
        if (Settings.Default.WindowPosition != Rectangle.Empty &&
            IsVisibleOnAnyScreen(Settings.Default.WindowPosition))
        {
            // first set the bounds
            this.StartPosition = FormStartPosition.Manual;
            this.DesktopBounds = Settings.Default.WindowPosition;

            // afterwards set the window state to the saved value (which could be Maximized)
            this.WindowState = Settings.Default.WindowState;
        }
        else
        {
            // this resets the upper left corner of the window to windows standards
            this.StartPosition = FormStartPosition.WindowsDefaultLocation;

            // we can still apply the saved size
            this.Size = Settings.Default.WindowPosition.Size;
        }
    }

    private bool IsVisibleOnAnyScreen(Rectangle rect)
    {
        foreach (Screen screen in Screen.AllScreens)
        {
            if (screen.WorkingArea.IntersectsWith(rect))
            {
                return true;
            }
        }

        return false;
    }

    protected override void OnClosed(EventArgs e)
    {
        base.OnClosed(e);

        // only save the WindowState if Normal or Maximized
        switch (this.WindowState)
        {
            case FormWindowState.Normal:
            case FormWindowState.Maximized:
                Settings.Default.WindowState = this.WindowState;
                break;

            default:
                Settings.Default.WindowState = FormWindowState.Normal;
                break;
        }

        // reset window state to normal to get the correct bounds
        // also make the form invisible to prevent distracting the user
        this.Visible = false;
        this.WindowState = FormWindowState.Normal;

        Settings.Default.WindowPosition = this.DesktopBounds;
        Settings.Default.Save();
    }
}

<?xml version='1.0' encoding='utf-8'?>
<SettingsFile xmlns="http://schemas.microsoft.com/VisualStudio/2004/01/settings" CurrentProfile="(Default)" GeneratedClassNamespace="ScreenTest" GeneratedClassName="Settings">
    <Profiles />
    <Settings>
        <Setting Name="WindowPosition" Type="System.Drawing.Rectangle" Scope="User">
            <Value Profile="(Default)">0, 0, 0, 0</Value>
        </Setting>
        <Setting Name="WindowState" Type="System.Windows.Forms.FormWindowState" Scope="User">
            <Value Profile="(Default)">Normal</Value>
        </Setting>
    </Settings>
</SettingsFile>