Create a copy in ~/
Create your ~/.themes
directory and copy the original Ambiance theme to it.
mkdir ~/.themes
cp -R /usr/share/themes/Ambiance ~/.themes/
Change the background color for the whole theme
If you want to change the base color for the whole theme, edit the base_color (Hex notation #??????) in gtk-main.css
. This changes the background color of other applications (eg: gedit) as well.
gedit ~/.themes/Ambiance/gtk-3.0/gtk-main.css
Change this line:
@define-color base_color #ffffff;
For this one:
@define-color base_color #C7EDCC
;
for more details see: http://askubuntu.com/questions/465908/how-to-change-background-of-nautilus-in-ubuntu-14-04