Moon DK-2019-1: 接触角(Contact angle)和差示扫描量热法(DSC)

SemiconductorPhysics

已于 2022-06-05 11:36:32 修改

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分类专栏：机理文章标签：接触角

于 2022-06-01 15:30:00 首次发布

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paper 1

Y. W. Han, S. J. Jeon, H. S. Lee, H. Park, K. S. Kim, H.-W. Lee and D. K. Moon, Evaporation-Free Nonfullerene Flexible Organic Solar Cell Modules Manufactured by An All-Solution Process, Adv. Energy Mater., 2019, 9(42): 1902065. (DOI: https://doi.org/https://doi.org/10.1002/aenm.201902065)

A low χ value leads to a too high miscible for the blend films.

The homogeneous phase with smaller interfacial area resulted too high miscible properties would hinder exciton dissociation at interface between donor and acceptor.

However, a too high χ value implies a too pure phase and potentially severe phase segregation, which leads to quench morphology.

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paper 2

R. Ma, T. Yang, Y. Xiao, T. Liu, G. Zhang, Z. Luo, G. Li, X. Lu, H. Yan and B. Tang, Air-Processed Efficient Organic Solar Cells from Aromatic Hydrocarbon Solvent without Solvent Additive or Post-Treatment: Insights into Solvent Effect on Morphology, Energy Environ. Mater., 2021, n/a(n/a). (DOI: https://doi.org/https://doi.org/10.1002/eem2.12226)
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paper 3

J. Comyn, Contact angles and adhesive bonding, Int. J. Adhes. Adhes., 1992, 12(3): 145. (DOI: https://doi.org/https://doi.org/10.1016/0143-7496(92)90045-W)

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Surface Tension数据

https://www.dataphysics-instruments.com/Downloads/Surface-Tensions-Energies.pdf
https://www.accudynetest.com/surface_tension_table.html
ref:
差示扫描量热法（DSC）测量物质的纯度的原理及实验方法
https://cn.insci.cn/materials_science_35959.html

求解代码

基于MATLAB

syms gamma_d gamma_p positive

%% 基于水water和乙二醇ethylene glycol
%% 输入数据这里：角度（°）
theta_Water = 105.57;
theta_EG = 76.60;

%% 水water和乙二醇ethylene glycol的数据
gamma_Water = 72.8; 
gamma_d_Water = 21.8;
gamma_p_Water = 51.0;

gamma_EG = 48;
gamma_d_EG = 29;
gamma_p_EG = 19;

%% 计算公式
eqn1 = gamma_Water*(cosd(theta_Water)+1) ==...
4*gamma_d_Water* gamma_d/( gamma_d_Water+gamma_d) +...
4*gamma_p_Water* gamma_p/( gamma_p_Water+gamma_p);

eqn2 = gamma_EG*(cosd(theta_EG)+1) ==...
4*gamma_d_EG* gamma_d/( gamma_d_EG+gamma_d) +...
4*gamma_p_EG* gamma_p/( gamma_p_EG+gamma_p);

%% 求解
S = solve([eqn1,eqn2],[gamma_d,gamma_p],'Real',true);

gamma = double(S.gamma_d + S.gamma_p);