ORA-12514: TNS:listener does not currently know of service requested in connect 错误

  这个错误是因为Listener出了问题，请检查一下你的listener.ora文件，看下是否存在如下配置：

SID_LIST_LISTENER =
  (SID_LIST =
    (SID_DESC =
      (SID_NAME = PLSExtProc)
      (ORACLE_HOME = E:/oracle/product/10.2.0/db_1)
      (PROGRAM = extproc)
    )
)

       如果说是这样，那么请将一段改成

SID_LIST_LISTENER =
 (SID_LIST =
 (SID_DESC =
  (SID_NAME = PLSExtProc)
  (ORACLE_HOME = E:/oracle/product/10.2.0/db_1)
  (PROGRAM = extproc)
  ) (SID_DESC =
     (GLOBAL_DBNAME = ORCL)
     (ORACLE_HOME = E:/oracle/product/10.2.0/db_1)
     (SID_NAME = ORCL)
  )
)
         这样以后，关掉Service和LISTENER。再启动Service和LISTENER，这样应该就可以了，注意顺序。