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Issue: There is no item category assigned to account
Solution 1
SPRO-->Financial Accounting (NEW)--> Special Purpose Ledger-->Actual Postings-->Settings for Accounting Integration-->Document Splitting-->Classify G/L accounts for document splitting.
Here you need to maintain the G/L account and assign item category for the same.
Solution 2
SPRO---Financial Accounting(new)——General Ledger Accounting(new)——Business Transations——Document Splitting——Activate Document Splitting, 再点击Deactivation per company code.,选中自己的公司,打钩,激活Splitting.