LGWR SYNC AFFIRM in Oracle Data Guard is used for zero data loss. How does one ensure zero data loss? Well, the redo block generated at the primary has to reach the standby across the network (that's where the SYNC part comes in - i.e. it is a synchronous network call), and then the block has to be written on disk on the standby (that's where the AFFIRM part comes in) - typically on a standby redo log.

Can you have LGWR SYNC NOAFFIRM? Yes sure. Then you will have synchronous network transport, but the only thing you are guaranteed is that the block has reached the remote standby's memory. It has not been written on to disk yet. So not really a zero data loss solution (e.g. what if the standby instance crashes before the disk I/O).

To sum up -> LGWR SYNC AFFIRM means primary transaction commits are waiting for ntk I/O + disk I/O acks. LGWR SYNC NOAFFIRM means primary transaction commits are waiting for ntk I/O only.