1 You can explicitly add it with the following command:
:badd file
2 Delete a buffer,The :bdelete command deletes a buffer,You can specify the buff by name
:bdelete file.c
Or by number:
:bdelete 3
:3 bdelete
You can also delete a whole range of buffers ,as following:
:1,3 bdelete
3 :ball command opens a window for each buffer