该研究通过FTIR、DTG和XRD分析及分子动力学模拟，探讨了吖啶橙在高电荷膨胀粘土中的吸附机制。在较低吸附覆盖率下，吸附主要归因于离子交换，形成倾斜双分子构型；当吸附量增加时，预测在蒙脱石层间会形成水平双层结构。
摘要：
In this study,the mechanism of acridine orange(AO) interaction into a high-charge swelling clay and its interlayer configuration was studied by FTIR,DTG,and XRD analyses and assisted by molecular dynamic simulation.At a lower surface coverage,the uptake of AO was mainly attributed to cation exchange with the intercalated AO forming a tilted dimer configuration.At higher AO uptake levels,a horizontal bilayer AO formation would be anticipated in the interlayer of montmorillonite.
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