摘要:
α-Bromo-4-nitrcstilbenes and diphenylacetylenes were prepared by utilizing the modified Wittig reaction.Diethyl a-bromo-p-nitrobenzylphosphonate [2] was obtained quantitatively by bromination of diethyl p-nitrobenzylphosphonate [1].Treatment of [2] with aromatic aldehydes in the presence of an equivalent amount of sodium alkoxide in alcohol at room temperature gave the corresponding a-bromo-4-nitrostilbenes in good yield.The use of two equivalent amounts of base gave diphenylacetylenes. Similarly the reaction of α-iodo-p-nitrobenzylphosphonate with aromatic aldehydes was investigated.
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