New-Datastore
Creates a new datastore.
i.e. New-Datastore -VMHost $host -Name Datastore -Path $scsiLun.CanonicalName -Vmfs -FileSystemVersion 3
https://pubs.vmware.com/vsphere-50/index.jsp?topic=%2Fcom.vmware.powercli.cmdletref.doc_50%2FNew-Datastore.html