摘要:
Gas-phase electron-diffraction data and high-level quantum chemical calculations have been used to study the conformational behaviour ofN-azidomethylpyrrolidine. The two most stable conformers with a relative abundance of about 80% at 298 K possessgaucheorientation of the azidomethyl group around the C–Npyrbond (C–Nazidogauchewith respect to the endocyclic Npyr–C bond). This orientation is a strong manifestation of an anomeric effect. The influence of the anomeric effect is also reflected in shortening of the C–Npyrbond and lengthening of the C–Nazidobond as compared to such bonds in other compounds.
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