摘要:
The absolute intensities of the fundamental infrared absorption bands of SiF4, CF4, and SF6were measured utilizing the pressure broadening technique. The effective bond moments, μ0, and bond moment derivatives, u/r,are calculated as a function of the most general potential constants. Based on a valence force field plus repulsion between nonbonded atoms, the most probable values (first column) and the alternatives (second column) are as follows:μ0=2.3d3.3dSiF4u/r=7.49d/A3.66d/Aμ0=1.12d2.36dCF4u/r=4.88d/A3.35d/Aμ0=2.65d0.65dSF6u/r=3.85d/A6.58d/AThe results are discussed.
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