You do not invoke the pyc file. It's the .py file that's invoked. Python is an interpreted language.
A simpler way to make a python exectuable (explained):
1) Add #!/usr/bin/env python at the top of your python executable file (eg. main.py) (it uses the default python - eg. if using arch, that's py3 instead of py2. You can explicitly tell it to run python2/python3 by replacing python with it's version: ex. python2.7)
2) Write the code. If the script is directly invoked, __name__ variable becomes equal to the string '__main__' thus the idiom: if __name__ == '__main__':. You can add all the logic that relates to your script being directly invoked in this if-block. This keeps your executable importable.
3) Make it executable 'chmod +x main.py'
4) Call the script: ./main.py args args