signature=a15ecfd7ce7aa13ed5fb3ab5b4058aab,A New Lyotropic Liquid Crystalline System: Oligo(ethylene...

摘要：

Coordinated water molecules induce the aggregation and self-assembly of the lyotropic liquid crystalline phase formed from non-ionic surfactants CnH2n+1(CH2CH2O)mOH and transition metal aqua complexes ([Ni(H2O)6](NO3)2, [Co(H2O)6](NO3)2, [Cd(H2O)4](NO3)2, and [Co(H2O)6]Cl2) into hexagonal (see schematic representation) and/or cubic structures. While the NiII and CoII complexes undergo recrystallization and phase separation at high complex concentrations, the ZnII and CdII complexes form cubic phases above metal/surfactant molar ratios of 3.2/1 at room temperature.

展开