c 发ajax get氢气,甲烷2f氢气吸附模型与存储过程热效应分析.pdf

The research of adsorption model for methane/hydrogen

and thermal effects on storage process

Abstract

Storage by adsorption of hydrogen/methane on carbon-based material such as activated

carbon has a potential application while comparing with other storage methods. However, in

practice, adsorption storage still faces such critical issues as the low storage density and thermal

effect of the storage system on the adsorption process. This paper carries out the research in

following aspects:

(1) Analysis of adsorption equilibrium model of supercritical gas on activated carbon. Ajax

Activated carbon which has a specific surface area about 1200m2 g1 was selected as an

adsorbent, isotherms of excess adsorption amount of methane were measured at temperature

from 268.15K-338.15K and pressure up to 12.5MPa. Comparisons were made between

experimental data and those predicted by Langmuir, Langmuir-Freundlich and Toth models.

Isosteric heats of methane adsorption on Ajax activated carbon were determined by adsorption

isosteres on the absolute amounts. Results show that Toth equation performs well in predicting

the equilibrium data in the whole pressure range 0-10MPa, but the results from

Langmuir-Freundlich equation have higher prediction accuracies while the pressure gets higher.

The adsorbed phase densities of supercritical methane on the activated carbon vary with

equilibrium temperatures and pressures, the mean value of isosteric heat of adsorption set by

absolute amounts is about 15.72 kJ mol1 , which is smaller than that plotted from the excess

amounts.

(2) Analysis of the