This is not something that can be managed by cron, but it can be managed by the Power Management Utilities (pm-utils). When reading man pm-action, you find:
/etc/pm/sleep.d, /usr/lib/pm-utils/sleep.d:
Programs in these directories (called hooks) are combined and executed in C sort order before suspend and hibernate with as argument suspend or hibernate. Afterwards, they are called in reverse order with argument resume and thaw respectively. If both directories contain a similar named file, the one in /etc/pm/sleep.d will get preference. It is possible to disable a hook in
the distribution directory by putting a non-executable file in /etc/pm/sleep.d, or by adding it to the HOOK_BLACKLIST configuration variable.
So all you need to do is create a script in /etc/pm/sleep.d that looks like this:
#!/usr/bin/env bash
action="$1"
case "$action" in
suspend)
# List programs to run before, the system suspends
# to ram; some folks call this "sleep"
;;
resume)
# List of programs to when the systems "resumes"
# after being suspended
;;
hibernate)
# List of programs to run before the system hibernates
# to disk; includes power-off, looks like shutdown
;;
thaw)
# List of programs to run when the system wakes
# up from hibernation
;;
esac
Obviously, you can alter this if you do not want to distinguish between suspend and hibernate, or resume and thaw into something like:
#!/usr/bin/env bash
action="$1"
case "$action" in
suspend|hibernate) stuff ;;
resume|thaw) stuff ;;
esac