I have to say this first: DataSet.xsd is disgusting, it makes simple things complicated.
In Visual Studio 2010 with AnkhSVN plugin, I can't do this: right click->view history->right click->show changes, seems that this method only works for text files like .cs.
I want to see SQL changes between different versions of dataset.xsd, I don't know how to accomplish this in Visual Studio 2010.
Note this: you can open the *.xsd file under file system with text editor like Notepadd++ to see SQL.
Final solution: you can do it in VS indeed, like this: