There're some terms in Data structure alignment we must know:
1. A memory address a, is said to be n-byte aligned when n is a power of two and a is a multiple of n bytes. In this context a byte is the smallest unit of memory access, i.e. each memory address specifies a different byte. An n-byte aligned address would have log2(n) least-significant zeros when expressed in binary.
2. A memory access is said to be aligned when the datum being accessed is n bytes long and the datum address is n-byte aligned. When a memory access is not aligned, it is said to be misaligned. Note that by definition byte memory accesses are always aligned.
3. A memory pointer that refers to primitive data that is n bytes long is said to be aligned if it is only allowed to contain addresses that are n-byte aligned, otherwise it is said to be unaligned. A memory pointer that refers to a data aggregate (a data structure or array) is aligned if (and only if) each primitive datum in the aggregate is aligned.
4. The type of each member of the structure usually has a default alignment, meaning that it will, unless otherwise requested by the programmer, be aligned on a pre-determined boundary. The following typical alignments are valid for compilers from Microsoft (Visual C++), Borland/CodeGear (C++Builder), Digital Mars (DMC) and GNU (GCC) when compiling for 32-bit x86:
A char (one byte) will be 1-byte aligned.
A short (two bytes) will be 2-byte aligned.
An int (four bytes) will be 4-byte aligned.
A long (four bytes) will be 4-byte aligned.
A float (four bytes) will be 4-byte aligned.
A double (eight bytes) will be 8-byte aligned on Windows and 4-byte aligned on Linux (8-byte with -malign-double compile time option).
A long double (ten bytes with C++Builder and DMC, eight bytes with Visual C++, twelve bytes with GCC) will be 8-byte aligned with C++Builder, 2-byte aligned with DMC, 8-byte aligned with Visual C++ and 4-byte aligned with GCC.
Any pointer (four bytes) will be 4-byte aligned. (e.g.: char*, int*)
The only notable difference in alignment for a 64-bit system when compared to a 32-bit system is:
A long (eight bytes) will be 8-byte aligned.
A double (eight bytes) will be 8-byte aligned.
A long double (eight bytes with Visual C++, sixteen bytes with GCC) will be 8-byte aligned with Visual C++ and 16-byte aligned with GCC.
Any pointer (eight bytes) will be 8-byte aligned.
5. It is important to note that the last member is padded with the number of bytes required so that the total size of the structure should be a multiple of the largest alignment of any structure member.