Magnetically enhanced thermoelectrics

最新推荐文章于 2024-11-05 15:26:40 发布

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最新推荐文章于 2024-11-05 15:26:40 发布

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本文链接：https://blog.csdn.net/amberheping/article/details/127746992

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本文探讨了磁性对热电材料性能的影响，包括通过带隙工程和声子工程优化热电性能，以及磁性粒子如何改变载流子浓度和散射。重点介绍了超顺磁在热电材料中的作用，如Co、Fe、Ni纳米粒子掺杂Ba0.3In0.3Co4Sb12导致的性能变化，并讨论了磁性转变如何增强热电性能，以及外部磁场对特定拓扑半金属的热电电磁效应。

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1、two effective approaches that optimize TE performance

One is band engineering, which is performed to enhance the PF through elemental doping at the atomic/molecular scale. Although the electronic band feature is an intrinsic property of a given TE material, it can be modified to some degree. The distortion of the electronic density of states (DOS) can effectively increase α, maintaining a relatively high σ. The charge density wave instability approach creates a high α . Large valley degeneracies and multiple electronic valence bands also provide high α and σ values.

The other approach is phonon engineering, which mainly reduces $\kappa _{L}$ by improving interfacial scattering at the nanometer scale. In order to reduce κ, in particular $\kappa _{L}$ , the enhancement of phonon scattering by the introduction of grain boundaries and defects is regarded as a useful method. Giant anharmonic vibration can also decrease $\kappa _{L}$ . All scale hierarchical architectures usually scatter phonons with long mean free paths . In addition, an intrinsically low κ is also required in some copper chalcogenides due to the liquid-like behavior of copper ions

2、对于热电材料中存在磁性的粒子的影响：

磁性的粒子将会存在一个微观的磁场 $H_{A}$ ，这个微观的磁场将会对载流子产生影响。由于这个微观磁场方向的不确定，载流子的速度方向至少有3中，第一种是与磁场的方向平行，这种载流子将不会受到微观磁场的影响；第二种是与磁场垂直，这种粒子将会受到洛伦兹力的影响，将会走圆形路径；第三种是与磁场既有平行的方向，又有垂直的方向，将会走螺旋线的方向。因此，存在磁性的粒子将会改变载流子的浓度，进而影响S和 $\sigma$ 。同时磁性粒子将会造成载流子的散射，减少 $\kappa$ 。

3、超顺磁增强热电性能

（1）超顺磁的的行为

单畴粒子在任何磁场中都能够被均一的磁化
推导：什么情况下能够变成超顺磁态

(2)电子的多重散射行为

If the reversal time of the magnetic moment is shorter than that of the measurement scale under an external magnetic field, the system is in a superparamagnetic state.Otherwise, it is in a so-called blocked state.
$T_{B}=\frac{KV}{k_{B}\ln \left ( \tau _{m}/\tau _{0} \right )}$ $\tau _{m}$ 是特征时间， $\tau _{0}$ 是测量时间， $T_{B}$ 是阻塞温度，在阻塞温度以上是超顺磁态
由于纳米粒子的超顺磁状态（