var departmentidList = List.Where((x, i) => bMS_Project_ProjectPeopleList.FindIndex(z => z.F_PeopleDepartment == x.F_PeopleDepartment) == i).Select(t => t.F_PeopleDepartment).ToList();
var departmentidList2 = List.GroupBy(d => d.F_PeopleDepartment).Select(d => d.Key).ToList();