volatile多线程中一定write优先于read吗？

不一定。

如下测试代码：

int a = 0;
volatile int b = 0;
@Test
public void testVolatile() throws InterruptedException {
    Thread thread1 = new Thread(() -> sleepAndCount());
    Thread thread2 = new Thread(() -> sleepAndRead());
    thread1.start();
    thread2.start();
    thread1.join();
    thread2.join();
}

private void sleepAndCount() {
    System.out.println("++a:"+ ++a);
    System.out.println("++b:"+ ++b);
}

private void sleepAndRead() {
    System.out.println("b:"+b);
    System.out.println("a:"+a);

}

输出结果：