revtex has its own rule macros. Do not load the booktabs package and use:
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CODE:
SELECT ALL •
OPEN IN ONLINE LATEX EDITOR
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\begin{tabular}{ccc}\toprule
\multicolumn{3}{r}{$k_{20}+k_{21}$($\times$10$^{-9}$cm$^{3}$s$^{-1}$)} \\\cline{2-3}
Neutral & Default & New \\\colrule
Kr &4.02 $\pm$ 0.46~ & 4.17 $\pm$ 0.49 \\
Xe & 6.11 $\pm$ 0.72& 6.39 $\pm$ 0.76\\\botrule
\end{tabular}