You need to login as SSO admin@system-domain, then add a user who is vCenter administrator.
After user added, logout and then login as administrator,then you will found the vCenter5.1 would be discovered automatically. And will show in the "Inventory lists".
Will show the picture here later.
如下是相关截图供参考。
1、SSO用户及组管理:
2、添加SSO用户,该用户要求是vCenter管理员:
3、使用新的用户名重新login SSO:
4、至此,我们即可以像以往使用vSphere Client客户端一样开始使用Web Client管理vCenter了: