raw_list = [["百度", "CPY"], ["京东", "CPY"], ["黄轩", "PN"], ["百度", "CPY"]]
new_list = [list(t) for t in set(tuple(_) for _ in raw_list)]
有序方法
new_list.sort(key=raw_list.index)
数组
import numpy as np
arr = np.array([[1, 2],[3, 4],[5, 6],[7, 8],[3, 4],[1, 2]])
print(np.array(list(set([tuple(t) for t in arr]))))