python读取word文档报错：KeyError: “There is no item named ‘word/NULL‘ in the archive“

使用docx读取word文档时出错

import docx
document = docx.Document("word.docx")

出错日志：

Traceback (most recent call last):
  File "D:\cv\test\test\test85.py", line 19, in <module>
    document = docx.Document(src)
  File "C:\Users\hxm\AppData\Roaming\Python\Python310\site-packages\docx\api.py", line 25, in Document
    document_part = Package.open(docx).main_document_part
  File "C:\Users\hxm\AppData\Roaming\Python\Python310\site-packages\docx\opc\package.py", line 128, in open
    pkg_reader = PackageReader.from_file(pkg_file)
  File "C:\Users\hxm\AppData\Roaming\Python\Python310\site-packages\docx\opc\pkgreader.py", line 35, in from_file
    sparts = PackageReader._load_serialized_parts(
  File "C:\Users\hxm\AppData\Roaming\Python\Python310\site-packages\docx\opc\pkgreader.py", line 69, in _load_serialized_parts
    for partname, blob, reltype, srels in part_walker:
  File "C:\Users\hxm\AppData\Roaming\Python\Python310\site-packages\docx\opc\pkgreader.py", line 110, in _walk_phys_parts
    for partname, blob, reltype, srels in next_walker:
  File "C:\Users\hxm\AppData\Roaming\Python\Python310\site-packages\docx\opc\pkgreader.py", line 105, in _walk_phys_parts
    blob = phys_reader.blob_for(partname)
  File "C:\Users\hxm\AppData\Roaming\Python\Python310\site-packages\docx\opc\phys_pkg.py", line 108, in blob_for
    return self._zipf.read(pack_uri.membername)
  File "D:\soft\miniconda3\lib\zipfile.py", line 1475, in read
    with self.open(name, "r", pwd) as fp:
  File "D:\soft\miniconda3\lib\zipfile.py", line 1514, in open
    zinfo = self.getinfo(name)
  File "D:\soft\miniconda3\lib\zipfile.py", line 1441, in getinfo
    raise KeyError(
KeyError: "There is no item named 'word/NULL' in the archive"

word的docx格式的文档，实际是zip格式文件，可用zip工具解压。所以，修改后缀名.zip，然后解压文件，得到解压后的文件，大部分为xml文件。

其中word/document.xml是主文件，但我这里出错的跟这个文件不相关，主要是查看word/_rels/document.xml.rels，这个文件主要是管理文档中的图片引用情况，查看详情可能会看到如下类似Target=“NULL”的行。

<n1:Relationship Id="rId19" Type="http://schemas.microsoft.com/office/2007/relationships/hdphoto" Target="NULL"/>

可以手动删除并保存，或者通过编写代码删除该行后，问题得到解决。

.docx为后缀名的word文档解压后的内部结构，更多的可参考docx格式文档详解：xml解析html还原