Inkscape – vector editor with xaml export feature http://inkscape.org/
A tool list:
http://blogs.msdn.com/b/mswanson/archive/2006/02/26/wpftoolsandcontrols.aspx
an adobe illustrator add-on: http://www.mikeswanson.com/XAMLExport/
A tool list:
http://www.graphspe.com/#/Home
svg to xaml online tool: http://www.graphspe.com/svg-to-xaml-converter#/Converter
svg print to xps then copy xaml: