We can change IDoc data in WE19, but actually it will generate a new IDoc based on we provided. Sometimes we'd like to change the IDoc(not posted to application yet) data directly for some reason, the process should be like follwing:
1. Run t-code WE02 to find an IDoc you want to change
2. Double click on the ICON ahead the segment name, and in the next screen choose "Data record" >> "Display -> Change"
3. then a window will popup, choose Continue
4. Now, the fields of choosed segment can be changed
5. At last, don't forget to Save! :)