General Contact

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_general/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_general/email');
 

Sales Representative

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_sales/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_sales/email');
 

Customer Support

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_support/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_support/email');
 

Custom Email 1

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_custom1/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_custom1/email');

 

Custom Email 2

/* Sender Name */
Mage::getStoreConfig('trans_email/ident_custom2/name'); 
/* Sender Email */
Mage::getStoreConfig('trans_email/ident_custom2/email');