系統識別號 | 640594 |
篇 名 | N,N,N′N′-四甲基乙二胺/CuBr2为催化体系的反向原子转移自由基聚合研究 |
並列篇名 | Reverse Atom Transfer Radical Polymerizations Using N, N, N′, N′-Teramethylethylendiamin/CuBr2 as the Catalyst |
作 者 | 潘凯(Kai Pan);江龙(Long Jiang);张娟(Juan Zhang);淡宜(Yi Dan) |
刊 名 | 四川大學學報(工程科學版) |
卷期/出版年月 | 39卷1期(2007/01) |
頁次 | 104-107 |
資料語文 | 中文 |
摘要 | 以偶氮二异丁睛(AIBN)为引发剂,N,N同,N′,N′-四甲基乙二胺(TMEDA)/CuBr2为催化剂,二甲苯为溶剂,分别进行了甲基丙烯酸甲酯(MMA)和丙烯酸丁酯(BA)的反向原子转移自由基聚合(RATRP)。聚合转化率和聚合物分子量及分子量分布测定结果表明,在非极性溶剂二甲苯中MMA的聚合,聚合物的数均分子量随转化率变化的线性关系较好,分子量分布较窄,聚合可控性较好;而BA的聚合可控性较差。此外,还对MMA最终聚合产物进行了1H-NMR分析,结果表明该反应属于RATRP反应机理,所得产物为无规立构结构。 The reverse atom transfer radical polymerizations of methyl methacrylate (MMA) and butyl acrylate (BA) were carried out at 80 using N, N, N′, N′-teramethylethylendiamin (TMEDA)/CuBr2 as the catalyst, AIBN as initiator, and xylene as solvent. GPC results and monomer conversion showed that the polymerization of MMA represents well controlled, the number-average molecular weight increases linearly with monomer conversion and during the whole polymerization, the polydispersities are low, however the polymerization of BA is uncontrolled. The resultant PMMA obtained from TMEDA/CuBr2 system was characterized by 1H-NMR spectroscopy, and the result showed that the polymerization kinetic is RATRP, and thepolymer is random structure. |
關鍵詞 | 反向原子转移自由基聚合,N,N,N′,N′-四甲基乙二胺,可控聚合;reverse atom transfer radical polymerization,N, N, N′, N′-teramethylethylendiamin,controlled polymerization |
CEPS分類 | 學科別>應用科學>綜合 |
四甲基乙二胺
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