WebException: 基础连接已经关闭: 发送时发生错误。异常处理

 HttpWebRequest req = (HttpWebRequest)WebRequest.Create(Picurl);
            req.Proxy = null;
            req.UserAgent = "Mozilla/5.0 (Windows NT 6.1; WOW64; rv:11.0) Gecko/20100101 Firefox/11.0";
            req.Headers.Add("Accept-Language", "zh-cn,en-us;q=0.8,zh-hk;q=0.6,ja;q=0.4,zh;q=0.2");
            req.Accept = "text/html,application/xhtml+xml,application/xml;q=0.9,*/*;q=0.8";
            ServicePointManager.ServerCertificateValidationCallback = delegate { return true; };
            ServicePointManager.SecurityProtocol = SecurityProtocolType.Ssl3;