处理接口里不支持的转义特殊字符:
NSCharacterSet *URLCombinedCharacterSet = [[NSCharacterSet characterSetWithCharactersInString:@"\"#%/,:<>?@[\\]^`{|}"] invertedSet];
NSString *newsignStr = [signStr stringByAddingPercentEncodingWithAllowedCharacters:URLCombinedCharacterSet];