该工作展示了BODIPY衍生物在合成方面的多功能性，特别是合成了具有不同meso位置功能基团的β,β'-BODIPY二聚体。这些二聚体在高效产率和短反应时间内通过单一平台得到。光物理研究表明，二聚体的吸收带位于约600nm，对应于电子耦合的单体以约30°的二面角排列，这一结果得到了理论模拟的支持。分子的发射性质随着溶剂极性的增加，显示出ICT状态的出现。
摘要：
The versatility in the synthesis of BODIPY derivatives in terms of functionalization is further demonstrated. Particularly, in this work β,β'-BODIPY dimers with varied functional groups in the meso-positions were synthetized in a very efficient yields and short reaction times from a single platform. A photophysical study was carried in all the compounds. The resultant dimers show absorption bands at around 600 nm as a consequence of electronically coupled monomers disposed with a dihedral angle of around 30, which is supported by theoretical simulations. The emission properties of these molecules are distinguished by the appearance of an ICT state as the polarity of the solvent increases.
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