XmlValidatingReader

private void Page_Load(object sender, System.EventArgs e)
  {
   FileStream stream = new FileStream(Server.MapPath("people.xml"), FileMode.Open);
   //创建XmlValidatingReader类的对象
   XmlValidatingReader vr = new XmlValidatingReader(stream, XmlNodeType.Element, null);
   //加载XML架构文档
   vr.Schemas.Add(null, Server.MapPath("people.xsd"));
   //说明验证的方式是根据XML架构
   vr.ValidationType = ValidationType.Schema;
   vr.ValidationEventHandler += new ValidationEventHandler(ValidationHandler);
   //对文档进行验证
   while(vr.Read());
   //显示验证过程完成
   Page.Response.Write("<b>Validation finished!<b>");
   //关闭打开的文件
   stream.Close();
  }

  private void ValidationHandler(object sender, ValidationEventArgs args)
  {
   //显示验证失败的消息
   Page.Response.Write("<b>Validation error: </b>" + args.Message + "<p>");
  }

people.xml：
<?xml version="1.0" encoding="utf-8"?>
<PEOPLE xmlns="http://tempuri.org/people.xsd">
    <PERSON>Tom</PERSON>
    <PERSON>Fred</PERSON>
</PEOPLE>