在原来的字符串中已使用\r\n换行，但字符串在转换到TextBox.Text值时，不知为什么少了\r，因而在保存前要把\n替换成\r\n

string s;
s = richTextBoxOut.Text;
s = s.Replace("\n", "\r\n");
File.WriteAllText("C:/Documents and Settings/Administrator/桌/aa.txt", s, Encoding.Unicode);

string tempS;
tempS = richTextBoxOut.Text.Replace("\n", "\r\n");
File.WriteAllText(C:/Documents and Settings/Administrator/桌/aa.txt", tempS, Encoding.Default);