cx_Freeze does not support building a single file exe, where all of the libraries for your application are embedded in one executable file. [There are modules that do this, but it's my understanding they use "hacks" that can get them flagged by antivirus software.]
You can use IExpress to compress the build directory from cx_Freeze into a self-extracting archive: an exe which unpacks your application into a temporary directory and runs it. IExpress is a utility that’s included with Windows, intended for making installers, but it works equally well if you tell it to run the cx_Freeze-built exe after extraction.
Alternatively, you can create a self extracting archive using 7zip. This is a bit more complex than using IExpress, but might provide more flexibility, and allows you to build your application using only open source tools.
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