PCI is a bus identifier. It refers to the PCI family of buses, which currently means PCI express (PCIe). You also might see USB here. (Not very common for video, but possible).
The other bits are just internal parameters to Windows, and have no guaranteed meaning. Generally, you expect a few bits here which would allow Windows to figure out it's a video card, and how that card is connected to the system (This tends to be more important for USB; USB hubs can form complex trees with 5 levels and 127 devices).
Given that, it's fairly obvious there are not nearly enough bits in there to have a globally unique ID. Also: in the Microsoft world, a globally unique ID is a GUID, and recognizable as such.