NPOI导入数据，判断EXCEL中是否存在重复数据，亲测可行

 //新建DataTable 储存 从excel中获取的e_id
	DataTable E_eid = new DataTable();
	 E_eid.Columns.Add("eid");
	 //循环E_ID添加进E_eid
	  for (int t = 0; t < dtData.Rows.Count; t++)
            {
		 DataRow dr = E_eid.NewRow();
		 dr["eid"] = dtData.Rows[t]["员工编号"].ToString();
		 E_eid.Rows.Add(dr);
	    }
	 //判断EXCEL中是否有重复e_id
         var hash = new HashSet<String>();
           foreach (DataRow row in E_eid.Rows)
           {
               var key = String.Concat(row["eid"]);
               if (hash.Add(key))
               {
                   //不重复
               }
               else
               {
               //返回重复数据
                   Response.Write("Excel中存在重复的员工编号："+key+"");
                   return;
               }
           }