给按钮加上如下代码即可:
this.button1.FlatStyle = FlatStyle.Flat;//样式
this.button1.ForeColor = Color.Transparent;//前景
this.button1.BackColor = Color.Transparent;//去背景
this.button1.FlatAppearance.BorderSize = 0;//去边线
this.button1.FlatAppearance.MouseOverBackColor = Color.Transparent;//鼠标经过
this.button1.FlatAppearance.MouseDownBackColor = Color.Transparent;//鼠标按下