效果如下:

代码如下:
# QDesktopWidget
import sys
from PyQt5.QtWidgets import QDesktopWidget,QMainWindow,QApplication
from PyQt5.QtGui import QIcon
class CenterForm(QMainWindow):
def __init__(self):
super(CenterForm,self).__init__()
# 设置主窗口的标题
self.setWindowTitle('让窗口居中')
# 设置窗口的尺寸
self.resize(400,300)
def center(self):
# 获取屏幕坐标系
screen = QDesktopWidget().screenGeometry()
# 获取窗口坐标系
size = self.geometry()
newLeft = int((screen.width() - size.width()) / 2)
newTop = int((screen.height() - size.height()) / 2)
self.move(newLeft,newTop)
if __name__ == '__main__':
app = QApplication(sys.argv)
main = CenterForm()
main.center()
main.show()
sys.exit(app.exec_())