The supplied data appears to be in the OLE2 Format. You are calling the part of POI that deals with OOXML (Office Open XML) Documents. You need to call a different part of POI to process this data (eg HSSF instead of XSSF)
网上查询也都是版本问题。
后来反复测试,发现xls导入没问题,但是将文件后缀直接改成xlsx导入就会报错。
将文件另存为xlsx后,再次导入,就不在报错了。