PostBackUrl="OrderWork.aspx?id=<%#Eval('OrderID') %>">
改成
PostBackUrl='<%#"OrderWork.aspx?id="+Eval('OrderID') %>'>
多个参数:
<asp:LinkButton ID="LinkButton1" PostBackUrl='<%#"OrderWork.aspx?id="+Eval("price")+"&name="+Eval("worth") %>' runat="server">LinkButton</asp:LinkButton>