<TextBox Text="{Binding FieldThatIAmBindingToo, UpdateSourceTrigger=PropertyChanged}">
<TextBox.InputBindings>
<KeyBinding Command="{Binding AddCommand}" Key="Return" />
</TextBox.InputBindings>
</TextBox>
Make sure to use UpdateSourceTrigger=PropertyChanged in your binding,
otherwise the property will not be updated until focus is lost, and pressing enter will not lose focus...