本文介绍了一种名为BZIC的新型有机光伏材料，其光学带隙低至1.45eV，能有效吸收600至850nm的光。由于噻吩和苯并三唑单元的共价锁定，增强了π-π相互作用。然而，富勒烯衍生物如PC61BM的电子亲和力不易调整，限制了开路电压。此外，它们在可见近红外区的吸收弱，容易形成晶粒，导致光吸收不足，短路电流密度下降。平面融合的中央单元通过π电子离域可以减小能隙，改善分子间的π-π堆积。
L. Feng, J. Yuan, Z. Zhang, H. Peng, Z. G. Zhang, S. Xu, Y. Liu, Y. Li and Y. Zou, Thieno[3,2-b]pyrrolo-Fused Pentacyclic Benzotriazole-Based Acceptor for Efficient Organic Photovoltaics, ACS Appl Mater Interfaces, 2017, 9(37): 31985. (DOI: https://doi.org/10.1021/acsami.7b10995)
要点
BZIC shows a low optical bandgap of 1.45 eV with broad and efficient absorption band from 600 to 850 nm due to increased π−π interactions by the covalently locking thiophene and benzotriazole units
However, electron affinities of fullerene derivatives cannot be well tuned, which limits open-circuit voltages (Voc).
fullerene derivatives like PC61BM show weak absorbance in the visible-near-infrared (Vis-NIR) region and have a tendency to form crystallites in active layer
Therefore, poor light absorption limits harvesting solar radiation efficiently and large phase separation restricts exciton diffusion and transport, which will decrease short-circuit current density (Jsc)
planar fused central units with a π-electron delocalization could decrease bandgap and improve π−π stacking among molecules
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