通过EventTrigger改变Border的背景颜色，必须先设置背景色，否则没有Background.Color属性

<Window x:Class="ControlTemplates.ButtonWithAnimations"
        xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
        xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
        Title="ButtonWithAnimations" Height="300" Width="300">
    <Window.Resources>
        <ControlTemplate x:Key="ButtonTemplate" TargetType="{x:Type Button}">
            <Border BorderBrush="Orange" BorderThickness="3" CornerRadius="2"
       Background="Red" TextBlock.Foreground="White" Name="Border">
                <Grid>
                    <Rectangle Name="FocusCue" Visibility="Hidden" Stroke="Black"
           StrokeThickness="1" StrokeDashArray="1 2"
           SnapsToDevicePixels="True" ></Rectangle>
                    <ContentPresenter RecognizesAccessKey="True"
         Margin="{TemplateBinding Padding}"></ContentPresenter>
                </Grid>
            </Border>
            <ControlTemplate.Triggers>
                <EventTrigger RoutedEvent="MouseEnter">
                    <BeginStoryboard>
                        <Storyboard>
                            <ColorAnimation Storyboard.TargetName="Border" Storyboard.TargetProperty="Background.Color"
                                            To="Blue" Duration="0:0:1" AutoReverse="True" RepeatBehavior="Forever"></ColorAnimation>
                        </Storyboard>
                    </BeginStoryboard>
                </EventTrigger>
                <EventTrigger RoutedEvent="MouseLeave">
                    <BeginStoryboard>
                        <Storyboard>
                            <ColorAnimation Storyboard.TargetName="Border" Storyboard.TargetProperty="Background.Color" Duration="0:0:0.5"></ColorAnimation>
                        </Storyboard>
                    </BeginStoryboard>
                </EventTrigger>
                <Trigger Property="IsPressed" Value="True">
                    <Setter TargetName="Border" Property="Background" Value="IndianRed" />
                    <Setter TargetName="Border" Property="BorderBrush" Value="DarkKhaki" />
                </Trigger>
                <Trigger Property="IsKeyboardFocused" Value="True">
                    <Setter TargetName="FocusCue" Property="Visibility" Value="Visible" />
                </Trigger>


            </ControlTemplate.Triggers>
        </ControlTemplate>

    </Window.Resources>
    <StackPanel Margin="10">
        <Button  Margin="10" Padding="5" Template="{StaticResource ButtonTemplate}" Name="cmdOne"
              >
            A Simple Button with a Custom Template
        </Button>
        <Button Margin="10" Padding="5" Template="{StaticResource ButtonTemplate}" Name="cmdTwo"
              >Another Button with a Custom Template</Button>

    </StackPanel>
</Window>