// 匹配至少5个纯字母的单词:
$str = 'baidu o2o b2b heol xiling shuai chou bage ss2';
$patt = '/\b[a-zA-Z]{5,}\b/';
preg_match_all($patt,$str,$res);
var_dump($res);
/*
array (size=1)
0 =>
array (size=3)
0 => string 'baidu' (length=5)
1 => string 'xiling' (length=6)
2 => string 'shuai' (length=5)
*/