python sample GUI Tkinter my use

# -*- coding: utf-8 -*-
#!/usr/bin/env python2
import sys
import os 
from Tkinter import *           # 导入 Tkinter 库
import time
import threading
root = Tk()                     # 初始化Tk()
root.title("GUI-Test-Read thermal")        # 设置窗口标题
root.geometry("500x300")        # 设置窗口大小 注意：是x 不是*
root.resizable(width=False, height=False) # 设置窗口是否可以变化长/宽，False不可变，True可变，默认为True
#root.iconbitmap('\heat.ico')
li     = ['1','2','3','4','5','6']
#movie  = ['7','8','9']
listb  = Listbox(root)      
#listb2 = Listbox(root)
for item in li:                 
    listb.insert(0,item)
 
#for item in movie:              
#    listb2.insert(0,item)  
def SaveLogfile(Str):
    f=open('.\\GUI_log.txt','a+')  
    print>>f,Str
    f.close()
def addlist():
    if listb.get(0)==&