xcode：no valid certificates with private keys found

You need to copy over the private key and certificate from your old Mac. Open Keychain Access on the old Mac and look in the Keys category of the login keychain: the key should be there. You need to export both the public and private key, then copy yourkey.pem and yourkey.p12 to the new Mac.

Importing them using Keychain Access will probably fail, at least under 10.6; you can use these commands instead:

security import yourkey.p12
security import yourkey.pem

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To generate a certificate on the Apple provisioning profile website, firstly you have to generate keys on your mac, then upload the public key. Apple will generate your certificates with this key. When you download your certificates, tu be able to use them you need to have the private key.

The error "XCode could not find a valid private-key/certificate pair for this profile in your keychain." means you don't have the private key.

Maybe because your Mac was reinstalled, maybe because this key was generated on another Mac. So to be able to use your certificates, you need to find this key and install it on the keychain.

If you can not find it you can generate new keys restart this process on the provisioning profile website and get new certificates you will able to use.