come from http://trac.adium.im/wiki/HiddenPreferences
XMPP Advanced Features (Default: Off)
To enable the advanced features (only the XML Console menu item right now), run the following command in Terminal:
defaults write com.adiumx.Adiumx AMXMPPShowAdvanced -bool YES
To disable it again, use:
defaults write com.adiumx.Adiumx AMXMPPShowAdvanced -bool NO