c语言xps,SCI论文中XPS这么写

原标题：SCI论文中XPS这么写

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前言：

关于论文写作这一块，我们也有些日子没跟大家分享了，今天跟大家分享下XPS实验结果如何描述。还是那句话，不积跬步无以至千里。我们将一点一点地把这些内容总结出来分享给大家，希望对大家有所帮助。

部分内容链接：

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1. 如何非常详细地描述XPS实验结果？

举例：X-ray photoelectronspectroscopy (XPS) was used to characterize theCu oxidation state. The coexistence ofCu(I) and Cu(II) infresh 3K-Cu-20TiO2 catalyst is evidenced by a shoulder observed on the main peak at931.6 eV (Figure2a), which is assigned toCu(I) species.The higher binding energy(BE) Cu 2p3/2 peak at 933.7 eV and its shakeup satellites are due toCu(II). TheCu(I) percentage infresh mesoporous 3K-Cu-20TiO2is estimated to be44%. Formesoporous 3K-Cu-50TiO2 , onlyCu(I) species are confirmed by XPS.TheseCu(I) species can be completelyoxidized to Cu(II) by oxygen at 250 °C as evidenced bytemperature programmed oxidation (TPO) and XPS data.

参考文献：Fan, J. et al., J. Am. Chem. Soc. 2009, 131, 15568 –15569.

提炼语言模板：

为什么做这个表征:X-ray photoelectronspectroscopy (XPS) was used to characterize the元素名称oxidation state.

得到了哪些信息，说明了哪些问题:

定性分析结果：The coexistence of元素化合态(I)and元素化合态(II)in样品名catalyst is evidenced by a shoulder observed on the main peak at峰位置eV (Figure2a), which is assigned to物种类型species. The higher binding energy (BE)峰属性peak at峰位置eV and its shakeup satellites are due to物种类型.

For样品名, only物种类型species are confirmed by XPS.

定量分析结果：The 物种类型 percentage in样品名is estimated to be 百分比.

从这些信息可还可以进一步得到什么：These物种类型species can be completely ___ to物种类型by处理方法as evidenced by表征手段。

2.不同文章中描写XPS结果可能详略不一，下面总结一些比较常见的写法供大家参考。

A. 主峰的定性分析(蓝色标记部分即为模板)：

TheIn 3dspectrum exhibits two contributions,3d5/2 and 3d3/2(resulting from the spin–orbit splitting), located at respectively444.7 and 452.2eV (Figure a, bottom), which can be assigned toInP. TheP2pspectrum (Figureb, bottom) clearly evidences the presence of two chemical environments forphosphorus atoms.The spectrum has been fitted by considering two resolved doublets(with a spin–orbit splitting of ∼0.9 eV between 2p3/2and 2p1/2). The first predominant doublet, present at128.7–129.6 eV, is characteristic ofInP. The second one, with a lower intensity, is located at higher binding energies,133.2–134.1eV, and corresponds, in agreement with the NMR results, tophosphorus in an oxidized environment, probably InPOx.

参考文献：, H. et al.J. Am. Chem. Soc, 2012, 134, 19701-19708

B. 处理前后XPS主峰的变动

1. The shift in BEs when comparing the neatZnO, CuO and the composite material () provides evidence of an interaction between theCu2+ and Zn2+ species. Inclusion ofLa into the system shifted theCu 2p3/2 peak maxima()from933.4 eV at low La loadings(1 wt%) to933.7 eV at higher La loadings(11 wt%) and was accompanied by a decrease inLa 3d5/2 peak maxima() from835.4 to835.1 eV, demonstrating an interaction betweenCuO and La2O3. The simultaneous and opposing changes toCu2p and La 3d BEs infer a decrease in electron density in theCu nucleus by increasingLa dopant concentration.La2O3 inclusion had no influence on theZnO peak maxima.

参考文献：Kam, R. et al., J. Catal. 2010, 273, 73-81.

2. Figure 5a summarizes the binding energy shifts measured with respect toAu-bulk (Au-4f7/2= 84.0 eV) as a function of cluster size and support. An increase in the BE shift with decreasing cluster size has been observed forAu/SiO2/n-Si(001) in accordance with Chusuei et al.with a maximum shiftof 0.88 eV at 1.5 nm.

参考文献：, B. J. Am. Chem. Soc.,2003,125 (42), pp 12928–12934

C. XPS全谱的描述

Surface analysis of the films was carried out using X-rayphotoelectron spectroscopy(Figure 3).TheSb 3d5/2 and 3d3/2 peaks are observed at529.7 and 537.3 eV,respectively.Additional peaks(525.9 and 535.4 eV) for Sb 3dindicate different chemical environmentsi.e., Sb−O and Sb−Te. The values of539.6 eV(3d3/2) and 530.3 eV (3d5/2)are reported forantimony oxide in the literature. A broad peak forSb 3d3/2is obtained due to overlapping with theO 1s (529.6 eV) peak. The twoTe 3dsignals, corresponding toTe−Sb andTe−O,are also seen. The values forTe−O, i.e., 584 eV (3d3/2) and 574 eV (3d5/2), are comparable to literature values of586 (3d3/2) and 576 eV (3d5/2).The presence of theO1s peak indicates that oxidation of the film takes place after exposure to the atmosphere.

参考文献：, S.J. Am. Chem. Soc., 2006, 128 (10), pp 3120–3121

D. 定量描述样品表面各元素含量

XPS revealed thatN-doping occurred at a temperature as low as 300 °C for GO annealed in NH3, with∼3.2% N detected in the sample(Figures b, a). N levels in GO sheets annealed in NH3 between 300 and 1100 °C were in a range of ∼3−5%,with500 °C annealing affording the highest N-doping levelof∼5% (Figure a). Comparing the oxygen levelsof GO samples annealed in NH3 and H2 at various temperatures, we found that the oxygen levels inGO annealed in NH3 were lower than inthoseannealed in H2 at the same temperatures except for 1100 °C (Figureb). This indicatedmore effective reduction effects of thermal annealing in NH3 than in H2 below∼1100 °C.

参考文献：Li, X. J.Am. Chem. Soc., 2009, 131(43), pp 15939–15944

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