abs和pc混在一起怎么解决_PC和ABS共混

E󰂀ect

of

reactive

compatibilizers

on

the

mechanical

properties

of

polycarbonate/poly(acrylonitrile-butadiene-

styrene)

blends

S.C.

Tjong*,

Y.Z.

Meng

1

Department

of

Physics

and

Materials

Science,

City

University

of

Hong

Kong,

Tat

Chee

Avenue,

Kowloon,

Hong

Kong

Received

6

July

1998;

received

in

revised

form

9

November

1998;

accepted

15

January

1999

Abstract

Polycarbonate

(PC)/poly(acrylonitrile-butadiene-styrene)

(ABS)

blends

compatibilized

with

both

maleic

anhydride

(MA)-grafted

polypropylene

and

solid

epoxy

resin

(bisphenol

type-A)

were

injection

molded.

The

e󰂀ects

of

the

compatibilizer

additions

on

the

morphology

and

mechanical

properties

of

the

PC/ABS

blends

were

investigated.

Tensile

and

Izod

impact

tests

revealed

that

the

addition

of

epoxy

at

2

phr

level

to

the

MA-grafted

PC/ABS

70/30

blend

led

to

a

signi®cant

increase

in

both

tensile

ductility

and

impact

strength.

Consequently,

epoxy

content

of

2

phr

level

was

added

to

all

the

blends

investigated.

Moreover,

tensile

tests

showed

that

the

yield

strength

of

PC

decreased

almost

linearly

with

increasing

ABS

content.

However,

the

tensile

modulus

showed

a

positive

deviation

from

the

rule

of

mixtures.

Both

MA

copolymer

and

epoxy

were

e󰂀ective

to

compatibilize

the

PC/ABS

blends

containing

ABS

content

up

to

30

wt%.

In

this

case,

the

impact

strength

of

these

compatibilized

blends

was

close

to

that

of

PC.

Above

40

wt%

ABS

content,

the

impact

strength

of

the

compatibilized

PC/ABS

blends

decreased

signi®cantly.

Scanning

electron

microscopic

examination

showed

that

the

ABS

tends

to

disperse

as

large

domains

in

PC

matrix

of

the

uncompatibilized

PC/ABS

blends.

However,

the

size

of

ABS

domains

of

PC/ABS

blends

with

ABS

󰁒

30

wt%

was

reduced

dramatically

owing

to

the

incorporation

of

both

compatilizers.

#

1999

Elsevier

Science

Ltd.

All

rights

reserved.

1.

Introduction

Bisphenol

A

polycarbonate

(PC)

is

a

widely

used

engineering

thermoplastic

because

it

possesses

several

distinct

properties

such

as

transparency,

dimensional

stability,

¯ame

retardance,

high

heat

distortion

tem-

perature,

and

high

impact

strength.

However,

PC

is

known

to

exhibit

poor

solvent

resistance,

poor

pro-

cessability

and

notch

sensitivity.

Though

PC

exhibits

tough

behavior

in

stress±strain

and

in

unnotched

impact

tests,

the

toughness

is

not

retained

under

con-

ditions

of

sharp

notches

and

thick

specimens.

Acrylonitrile-butadiene-styrene

(ABS)

copolymer

is

a

most

successful

rubber-toughened

thermoplastic,

and

has

several

attractive

properties

such

as

low

cost,

good

processability

and

notch

insensitive.

ABS

has

certain

limitations,

e.g.,

low

thermal

stability,

poor

¯ame

and

chemical

resistance.

The

combination

of

the

best

properties

of

PC

and

ABS

have

resulted

in

the

development

of

commercially

available

PC/ABS

blends

that

have

been

found

to

be

useful

in

many

European

Polymer

Journal

36

(2000)

123±129

0014-3057/99/$

-

see

front

matter

#

1999

Elsevier

Science

Ltd.

All

rights

reserved.

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